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Formation of Imidazolones by Ring Closure of α-Isocyanoamides: Exploring New Reactivities

Steven Frippiat 1 Claire Leterrier 1 Christine Baudequin 1 Christophe Hoarau 1 Laurent Bischoff 1
1 COBRA - Chimie Organique et Bioorganique : Réactivité et Analyse
Abstract : Base-mediated ring closure of α,α-disubstituted α-isocyanoamides with further electrophilic trapping has previously been explored, but with limited applications. In this work, we wished to unravel the reactivities of these compounds and, in particular, to allow palladium-catalyzed coupling at the C2 position.
Keywords : Isocyanides Imidazolones Lithium compounds Palladium catalysis Coupling
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Journal articles
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02548970
Contributor : Madeleine Roux-Merlin <>
Submitted on : Tuesday, April 21, 2020 - 10:07:49 AM
Last modification on : Thursday, July 2, 2020 - 3:29:23 AM

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Steven Frippiat, Claire Leterrier, Christine Baudequin, Christophe Hoarau, Laurent Bischoff. Formation of Imidazolones by Ring Closure of α-Isocyanoamides: Exploring New Reactivities. SYNLETT, Georg Thieme Verlag, 2020, (in press). ⟨10.1055/s-0040-1708015⟩. ⟨hal-02548970⟩

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