, Une partie du stage d'Helisoa Rakorondramaro était d'effectuer des scenarii d'accidents en réacteur semi-fermé de laboratoire (Figure 64)
, Evaluation économique des procédés en CFI 4
évaluation économique des procédés est situé au second semestre de la quatrième année de CFI, à savoir avant que les étudiants de CFI fassent leur choix entre les options génie des procédés, matériaux ou chimie fine. Le premier objectif est de montrer aux étudiants la méthodologie classique pour déterminer le coût du capital d'investissement et le coût opératoire d'un procédé chimique ,
, Edition Technip) mais aussi sur les livres anglosaxons :-Plant Design and Economics for Chemical Engineers de Max Peters, Klaus Timmerhaus et Ronald West aux éditions McGraw-Hill Education,-Product and Process Design Principles: Synthesis, Analysis and, En ce qui concerne les supports bilbiographiques j'ai utilisé le livre d'Alain Chauvel « Manuel d'évaluation économique des procédés
, Ces ouvrages représentent une source d'inspiration notamment sur la partie pédagogie mais aussi sur les différences entre les systèmes français et nord-américain
, PFD (Process Flow Diagram) et PID (Piping and Instrumentation Diagram), Les notions de mise à jour avec les différents indices (CE..), d'actualisation
Epoxidation of vegetable oils under microwave irradiation, Chemical engineering research and design, vol.92, issue.8, pp.1495-1502, 2014. ,
The limit of DSC as a Preliminary Tool to Determine the Safety Parameters?, Chemical Engineering Transactions, vol.36, pp.139-144 ,
Interaction of thermal and kinetic parameters for a liquid liquid reaction system: Application to vegetable oils epoxidation by peroxycarboxylic acid, Journal of the Taiwan Institute of Chemical Engineers, vol.45, pp.1449-1458, 2014. ,
Modeling and optimization of material/energy flow exchanges in an industrial park, Energy Procedia, vol.36, pp.243-252, 2013. ,
From Kinetic study to thermal safety assessment: application to peroxyformic acid synthesis, Industrial & Engineering Chemistry Research, vol.51, issue.43, pp.13999-14007, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-02138620
Modeling of a liquid-liquid-solid heterogeneous reaction system: application to the synthesis of peroxy fatty acids, Industrial & Engineering Chemistry Research, vol.51, issue.1, pp.189-201, 2012. ,
Batch and semi-batch partial oxidation of starch by hydrogen peroxide in the presence of iron tetrasulfophthalocyanine catalyst: the effect of ultrasound and catalyst addition policy, Industrial & Engineering Chemistry Research, vol.50, issue.2, pp.749-757, 2011. ,
Green process technology for peroxycarboxylic acids: estimation of kinetic and dispersion parameters aided by RTD measurements: green synthesis of peroxycarboxylic acids, Chemical Engineering Science, vol.66, pp.1038-1050, 2011. ,
URL : https://hal.archives-ouvertes.fr/hal-02151572
Modelling of Simultaneous Reaction and Diffusion in Chemical Reactors with Particle Size Distributions: Application of Ion-exchange Resins in Heterogeneous Catalysis, Chemical Engineering Transactions, vol.24, pp.139-144, 2011. ,
Renvall Functionality of Poly(?-hydroxyacrylic acid) as H 2 O 2 stabilizing agent, Oxidation Communication, pp.258-274, 2010. ,
Stability of hydrogen peroxide during perhydrolysis of carboxylic acids on acidic heterogeneous catalysts, Research on Chemical Intermediates, vol.36, issue.4, pp.389-401, 2010. ,
URL : https://hal.archives-ouvertes.fr/hal-02151573
A review: Catalytic synthesis and decomposition of peroxycarboxylic acids, Trends in chemical engineering, vol.13, pp.17-52, 2010. ,
Interaction of Intrinsic Kinetics and Internal Mass Transfer in Porous Ion-Exchange Catalysts: Green Synthesis of Peroxycarboxylic Acids, Chemical Engineering Science, vol.64, pp.4104-4114, 2009. ,
URL : https://hal.archives-ouvertes.fr/hal-02017721
Synthesis of Peroxypropionic Acid from Propionic Acid and Hydrogen Peroxide using heterogenous Catalysts, Chemical Engineering Journal, vol.147, pp.323-329, 2009. ,
Application of Linear Free-Energy Relations to Perhydrolysis of Different Carboxylic Acids over Homogeneous and Heterogeneous Catalysts, Journal of Molecular Catalysis A: Chemical, vol.303, pp.148-155, 2009. ,
Kinetic Study and Modeling of Peroxypropionic Acid Synthesis from Propionic Acid and Hydrogen Peroxide using Homogeneous Catalysts, Industrial & Engineering Chemistry Research, vol.47, issue.3, pp.656-664, 2008. ,
URL : https://hal.archives-ouvertes.fr/hal-02017711
Kinetic Study of Decomposition of Peroxypropionic acid in Liquid-Phase through Direct Analysis of Decomposition Products in Gas Phase, Chemical Engineering Science, vol.62, pp.5007-5012, 2007. ,
URL : https://hal.archives-ouvertes.fr/hal-02017689
Thermal safety assessment of epoxidized vegetable oils: key intermediates for CO2 valorization" Oral presentation for the JCAT 45 Journées de Calorimétrie et d'Analyse Thermique, 20 th23 rd, 2014. ,
Kinetic modelling of vegetable oil epoxydation" Poster presentation for the 21 st International Congress of Chemical and Process Engineering CHISA, 23 rd-27 th, 2014. ,
The limit of DSC as a Preliminary Tool to Determine the Safety Parameters, Oral presentation for 6 th International Conference on Safety & Environment in Process & Power Industry, 13 rd-16 th, 2014. ,
Economic analysis of methanol synthesis from CO 2 " Poster presentation for GPE, 4th International Congress on Green Process Engineering, 7 th-10 th, 2014. ,
INSA project management : COOLCAP" Poster presentation for GPE, 4th International Congress on Green Process Engineering, 7 th-10 th, 2014. ,
Coupling of the energy and mass balance: application to peroxycarboxylic acid synthesis" Oral presentation for 20 th International Congress of Chemical and Process Engineering CHISA, Investigation of energy and mass balance for the epoxidation of vegetable oils" Poster presentation for the XIV SFGP conference, 8 th-10 th October, vol.8, pp.12-14, 2011. ,
Green production of green compounds: Epoxidation of vegetable oils under microwave irradiation" Oral presentation for the International Congress on Green Process Engineering GPE2011, 2011. ,
Modelling of a liquid-liquidsolid heterogeneous reaction system: application to the synthesis of peroxy fatty acids" Oral presentation for the International Congress on Green Process Engineering GPE2011, 2011. ,
Modelling of simultaneous reaction and diffusion in chemical reactors with particle size distributions: application of ion-exchange resins in heterogeneous catalysis" Oral presentation for ICheaP10 International Conference, vol.22, 2011. ,
Epoxidation of vegetable oils under microwave irradiation in case of a liquid-liquid-solid reaction system" Oral presentation for Catalysis in Multiphase Reactors CAMURE-8 Conference, 2011. ,
Epoxidation of vegetable oils under microwave irradiation" Oral presentation for the Conference Catalysis for Renewable Sources: fuel, energy, chemicals, 2010. ,
Poster presentation for the 21 st International Symposium on Chemical Reaction Engineering, vol.13, 2010. ,
Transient techniques elucidate catalytic liquid-phase processes for green chemicals: perhydrolysis of carboxylic acids to percarboxylic acids" Oral presentation for the 19th International Congress of Chemical and Process Engineering CHISA 28 th, vol.23, 2009. ,
Application of Linear Free-Energy Relationships to Perhydrolysis of Different Carboxylic Acids over Homogeneous and Heterogeneous Catalysts" Poster presentation for the Europacat IX, 2009. ,
Interaction of intrinsic kinetics and internal mass transfer in porous ion-exchange catalysts: green synthesis of peroxycarboxylic acids" Oral presentation for the 5 th International Conference on Diffusion in Solids and Liquids, 2009. ,
Synthesis of peroxycarboxylic acids: from homogeneous to heterogeneous catalysts" Poster presentation for the 2 nd International Congress on Green Process Engineering, vol.14, 2009. ,
Utilization of Taft Equation: Kinetic Modelling of Carboxylic Acids Perhydrolysis over Heterogeneous and Homogeneous Catalysts" Oral presentation for the XVIII International Conference on Chemical Reactors, 2008. ,
Kinetic Study and Modeling of Perhydrolysis of Propionic Acid using Heterogeneous Catalyst" Poster presentation for the XVIII International Conference on Chemical Reactors, 2008. ,
Kinetic Study and Modeling of Peroxypropionic Acid Synthesis from Propionic Acid and Hydrogen Peroxide using Homogeneous Catalysts" Poster presentation for the Catalysis Concept, Complexity and Diversity in Catalysis, vol.12, 2007. ,
Kinetic Study of Decomposition of Peroxypropionic acid in Liquid-Phase through Direct Analysis of Decomposition Products in Gas Phase" Poster presentation for the 19 th, International Symposium on Chemical Reaction Engineering, 2006. ,
Optimization of the Synthesis of Peroxypropionic Acid by using Zeolite Catalysts" Poster presentation for the 4 th EFCATS School on catalysis, 2006. ,
Kinetic Study of Decomposition of Peroxypropionic Acid in LiquidPhase Through Direct Analysis of Decomposition Products in Gas Phase, Flash presentation for Åbo Akademi Process Chemistry Centre Annual Meeting, 2006. ,
La thèse a été encadrée par le professeur Ilka Turunen. Critiques dans différents journaux, Reviewer in International Journal of Chemical Kinetics, 2012. ,
, Reviewer in International Journal of Chemical Engineering, 2011.
, Reviewer in Reaction Kinetics, Mechanisms and Catalysis, 2012.
, Reviewer in Industrial & Engineering Chemistry Research, 2012.
, Reviewer in Chemical Engineering Science, 2011.
, Reviewer in Journal of Thermal Analysis and Calorimetry, 2011.
, Reviewer in Chemical Engineering Journal, 2014.
, Reviewer in Brazilian Journal of Chemical Engineering, 2010.
, Reviewer in Chemical Product and Process Modeling, 2010.
, Nanotechnology Reviews, 2014.
, Critiques dans différentes conférences internationales : Reviewer of abstracts for International Conference on Safety & Environment in Process & Power Industry-13-16, 0108.
, Président de session de JCAT 45 Journées de Calorimétrie et d'Analyse Thermique, 20 th23 rd, 2014.
, Membre du comité d'organisation de 43 rd ESReDA Seminar on Land Use Planning and Risk-Informed Decision Making-'Aménagement du Territoire et Prise de Décision en Maitrise de Risques' 22-23 Octobre, vol.23, 2007.
« Pursuing practical elegance in chemical synthesis, p.1807, 2005. ,
« Preparation of Aliphatic Peroxyacids, J. Org. Chem, vol.23, pp.1823-1826 ,
« Photochemical peroxide formation. IX. Oxidation of paraldehyde by molecular oxygen in ultraviolet light», Zeitschrift fuer Wissenschaftliche Photographie, Photophysik und Photochemie, n°36, p.119, 1937. ,
, Zeitschrift fuer Anorganische Chemie, vol.84, p.145, 1914.
Organic Peroxides, 1970. ,
Tracer studies in the formation and reactions of organic per-acids », Journal of the Chemical Society, p.1226, 1956. ,
Génie de la Réaction Chimique, vol.2, 1993. ,
Bestämning av syrets och koldioxidens löslighet i organiska vätskor, 2003. ,
MODEST-User's Guide, Profmath Oy, 1994. ,
Experimental study and mathematical modelling of organic decomposition reactions in liquid phase, Åbo Akademi, 2004. ,
« Preparation of peracetic acid from hydrogen peroxide, part II: Kinetics for spontaneous decomposition of peracetic acid in the liquid phase, Journal of Molecular Catalysis A: Chemical, vol.284, issue.2, pp.58-68, 2008. ,
, Sequential Proton Transfer Through Water Bridges in Acid-Base Reactions, vol.310, pp.83-86, 2005.
« Ring opening of decalin over zeolites: I. Activity and selectivity of proton-form zeolites », Journal of Catalysis, vol.222, issue.1, pp.65-79, 2004. ,
« Cyclization of citronellal over zeolites and mesoporous materials for production of isopulegol, Journal of Catalysis, vol.225, issue.1, pp.155-169, 2004. ,
,
« The development of the method of low-temperature peat pyrolysis on the basis of alumosilicate catalytic system, Chemical Engineering Journal, vol.134, pp.162-167, 2007. ,
, Catalytic pyrolysis of woody biomass in a fluidized bed reactor: Influence of the zeolite structure », Fuel, vol.87, pp.2493-2501, 2008.
« Kinetic of liquid-phase reactions catalyzed by acidic resins: the formation of peracetic acid for vegetable oil epoxidation, Applied Catalysis A: General, vol.197, issue.1, pp.165-173, 2000. ,
Infrared spectroscopy of ion exchange resins: chemical deterioration of the resins, Reactive and Functional Polymers, vol.53, pp.157-171, 2002. ,
« Kinetics study of esterification of acetic acid with isobutanol in the presence of amberlite catalyst, Applied Catalysis A: General, vol.239, issue.2, pp.141-148, 2003. ,
The kinetics of Some Industrial Heterogeneous Catalytic Reactions, Advances in Catalysis, 1979. ,
, Chem. Rev, vol.5, issue.3, pp.231-338, 1928.
, Chemical Kinetics, vol.3, 1987.
« Heterogeneous catalysis with nonuniformly reactive adsorbates, J. Phys. Chem, vol.92, pp.6970-6978, 1988. ,
Steric Effect in Organic Chemistry, 1956. ,
« Liquid-Phase Esterification of Propionic Acid with n-Butanol, Ind. Eng. Chem. Res, vol.40, pp.3281-3286, 2001. ,
, Kinetics of Hydrolysis of Benzaldehyde Dimethyl Acetal over Amberlite IR-120, vol.46, pp.1058-1062, 2007.
« Determination of Carboxylic Acid Dissociation Constants to 350 °C at 23 MPa by Potentiometric pH Measurements, J. Chem. Eng. Data, vol.49, issue.5, pp.1359-1363, 2004. ,
Chemical Reaction Engineering, vol.3, 1999. ,
, Les Réacteurs Chimiques. Editions TECHNIP, 2002.
« Esterification of different acids over heterogeneous and homogeneous catalysts and correlation with the Taft equation », Journal of Molecular Catalysis A: Chemical, pp.555-563, 2002. ,
« Kinetics of Formation of Peroxyacetic Acid, Russ J Gen Chem, vol.75, issue.7, pp.1125-1130, 2005. ,
« Kinetics of the acid-catalysed formation of aliphatic peracids from hydrogen peroxide and aliphatic acids in dioxan, Tetrahedron, vol.21, pp.3381-3386, 1965. ,
« Preparation of peracetic acid from hydrogen peroxide: Part I: Kinetics for peracetic acid synthesis and hydrolysis, Journal of Molecular Catalysis A: Chemical, vol.271, issue.2, pp.246-252, 2007. ,
Process for the preparation of peroxy acids. No. WO2007031596, 2007. ,
, Method for Preparing Peroxy Acetic Acid. No. CN1803771, 2006.
A new method for the preparation of peroxyacetic acid using solid superacid catalysts, Tetrahedron Letters, vol.44, pp.5535-5537, 2003. ,
Improvements in or relating to the oxidation of aliphatic carboxylic acids to peracids, vol.776758, 1957. ,
« Single pot synthesis of peroxyacetic acid from acetic acid and hydrogen peroxide using various solid acid catalysts, Catalysis Communications, vol.7, issue.11, pp.875-878, 2006. ,
« Rates of formation of peroxyacetic acid from hydrogen peroxide and acetic acid in the presence of metal(IV) phosphates », Journal of Molecular Catalysis A: Chemical, vol.186, issue.2, pp.127-133, 2002. ,
Bleaching detergent Composition. US 6159919, 1996. ,
Enzyme for the Production of Long Chain Peracid, 2010. ,
, Analysis of Aliphatic Per Acids, vol.20, pp.1061-1063, 1948.
« Analysis of solvent-free ethyl oleate enzymatic synthesis at equilibrium conditions, Enzyme and Microbial Technology, vol.38, issue.7, pp.914-920, 2006. ,
« Suspending of solid particles in liquid by agitators, Chemical Engineering Science, vol.8, pp.244-253, 1958. ,
, « Particle?Liquid Mass Transfer Coefficient in Two-/Three-Phase Stirred Tank Reactors, vol.41, pp.4141-4167, 2002.
« Particle liquid hydrodynamics and mass transfer in a stirred vessel, part 1. Particle liquid motion, Trans. Inst. Chem. Eng, vol.50, pp.132-146, 1972. ,
« Degradation of the oxirane ring of epoxidized vegetable oils in a liquid-liquid-solid heterogeneous reaction system, Chemical Engineering and Processing: Process Intensification, vol.46, issue.3, pp.210-221, 2007. ,
Moo-Young, « The continuous phase heat and mass-transfer properties of dispersions, Chemical Engineering Science, vol.16, issue.2, pp.39-54, 1961. ,
« Effects of the Stirred Tank's Design on Power Consumption and Mixing Time in Liquid Phase, Chem. Eng. Technol, vol.23, issue.7, pp.605-613, 2000. ,
Chemical properties handbook, 1999. ,
« Measurement of interfacial areas with the chemical method for a system with alternating dispersed phases, Chemical Engineering and Processing: Process Intensification, vol.39, issue.4, pp.299-314, 2000. ,
, The velocity of particles, drops and bubbles, vol.21, pp.9-14, 1987.
Liquid extraction, vol.2, 1963. ,
Physical rate processes in industrial fermentation-Part III: Mass transfer from fluids to solid particles suspended in mixing vessels, Trans. Inst. Chem. Engrs, vol.39, pp.363-368, 1961. ,
, A Steady-State Kinetic Model for Methanol Synthesis and the Water Gas Shift Reaction on a Commercial Cu/ZnO/Al2O3Catalyst », vol.161, pp.1-10, 1996.
Principles and Case Studies of Simultaneous Design, 2011. ,
, Controlled microwave heating in modern organic synthesis: highlights from the 2004-2008 literature, vol.13, pp.71-193, 2009.
, Microwave assisted organic synthesis-a review, vol.57, pp.9225-9283, 2001.
« Process Intensification of Reactive Distillation for the Synthesis of n-Propyl Propionate: The Effects of Microwave Radiation on Molecular Separation and Esterification Reaction, Ind. Eng. Chem. Res, vol.49, pp.10287-10296, 2010. ,
Kinetic and Mechanistic Investigation of MicrowaveAssisted Lipase Catalyzed Synthesis of Citronellyl Acetate, Ind. Eng. Chem. Res, vol.48, pp.7915-7922, 2009. ,
« Microwave-expedited olefin epoxidation over hydrotalcites using hydrogen peroxide and acetonitrile, Tetrahedron Letters, vol.43, pp.2909-2911, 2002. ,
Modeling of Microwave Assisted Epoxidation of Palm Acid Oil, American Journal of Applied Sciences, vol.8, issue.3, pp.217-229, 2011. ,
« Aromatic nitrations by mixed acid. Fast liquid-liquid reaction regime, Chemical Engineering and Processing: Process Intensification, vol.35, issue.2, pp.91-105, 1996. ,
, Thermal Safety of Chemical Processes: Risk Assessment and Process Design, 2008.
DOI : 10.1002/9783527621606
URL : https://onlinelibrary.wiley.com/doi/pdf/10.1002/9783527621606.fmatter
Homer Kissinger and the Kissinger equation, Thermochimica Acta, vol.540, pp.1-6, 2012. ,
DOI : 10.1016/j.tca.2012.04.008
« Lubricants from chemically modified vegetable oils, Bioresour. Technol, vol.101, issue.1, pp.245-254 ,
DOI : 10.1016/j.biortech.2009.08.035
« Oxygen Solubility Measurements in a MEA/H2O/CO2 Mixture, J. Chem. Eng. Data, vol.58, issue.5, pp.1117-1121, 2013. ,
DOI : 10.1021/je301077y
« Influence of Sulphuric Acid on Absorption Kinetic of Carbon Dioxide in Monoethanolamine, Procedia Engineering, vol.42, pp.397-407, 2012. ,
« High yield epoxidation of fatty acid methyl esters with performic acid generated in situ, Chemical Engineering Journal, vol.144, pp.466-475, 2008. ,