High pressure promoted dearomatization of nitroarenes by [4+2] cycloadditions with silyloxydienes

Batoul Rkein (1) , Romain Coffinier (1) , Marian Powderly (1) , Maxime Manneveau (1) , Morgane Sanselme , Muriel Durandetti (1) , Muriel Sebban (1) , Ghanem Hamdoun (1) , Hassan Oulyadi (1) , David Harrowven , Julien Legros (1) , Isabelle Chataigner (1, 2)

1 COBRA - Chimie Organique et Bioorganique : Réactivité et Analyse
2 LCT - Laboratoire de chimie théorique

Simple nitroarenes such as nitronaphthalenes and nitroquinolines smoothly undergo dearomatizing [4+2] cycloadditions with silyloxydienes under 16 kbar.

Domaines: Chimie organique

Batoul Rkein, Romain Coffinier, Marian Powderly, Maxime Manneveau, Morgane Sanselme, et al.. High pressure promoted dearomatization of nitroarenes by [4+2] cycloadditions with silyloxydienes. Chemical Communications, 2022, 58 (84), pp.11807-11810. ⟨10.1039/d2cc04778k⟩. ⟨hal-03854290⟩