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Multicomponent Catalytic Enantioselective Synthesis of Isoxazolidin‐5‐Ones

Abstract : We report herein a strategy to afford a multicomponent catalytic enantioselective synthesis of βsubstituted isoxazolidin-5-ones via a KMC process promoted by a suited cupreine used as bifunctional organocatalyst. The hydroxamic acid component, with a sterically hindered amide moiety, proved to be key for the successful formation and transformation of the obtained original N-amide isoxazolidin-5-ones.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-03322422
Contributor : Jean-François Brière Connect in order to contact the contributor
Submitted on : Thursday, August 19, 2021 - 9:59:23 AM
Last modification on : Tuesday, January 4, 2022 - 5:59:47 AM
Long-term archiving on: : Saturday, November 20, 2021 - 6:12:13 PM

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Julien Annibaletto, Thomas Martzel, Vincent Levacher, Sylvain Oudeyer, Jean-François Brière. Multicomponent Catalytic Enantioselective Synthesis of Isoxazolidin‐5‐Ones. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2021, 363, pp.4447-4451. ⟨10.1002/adsc.202100719⟩. ⟨hal-03322422⟩

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