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Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives

Emmanuel Deau 1 Alexandra Le Foll 1 Clémence Fouache 1 Emilie Corrot 1 Laetitia Bailly 1 Vincent Levacher 1 Pierric Marchand Florian Querniard Laurent Bischoff 1 Jean-François Brière 1
1 COBRA - Chimie Organique et Bioorganique : Réactivité et Analyse
Abstract : An unprecedented enantioselective conjugate addition reaction of sodium bisulfite to various nitrostyrenes occurred upon the influence of a bifunctional amino-thiourea organocatalyst; a strategy that opens a straightforward route to unprotected chiral taurine derivatives thanks to the reduction of the obtained β-nitroethanesulfonic acids into the corresponding amino derivatives.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-03322399
Contributor : Jean-François Brière Connect in order to contact the contributor
Submitted on : Thursday, August 19, 2021 - 9:53:48 AM
Last modification on : Tuesday, January 4, 2022 - 6:37:49 AM
Long-term archiving on: : Saturday, November 20, 2021 - 6:11:44 PM

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COMUE-NORMANDIE | INC-CNRS | INSA-ROUEN | ENSICAEN | UNIROUEN | COBRA | UNICAEN | INSA-GROUPE | CNRS | UNILEHAVRE

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Emmanuel Deau, Alexandra Le Foll, Clémence Fouache, Emilie Corrot, Laetitia Bailly, et al.. Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives. Chemical Communications, Royal Society of Chemistry, 2021, 57, pp.8348 - 8351. ⟨10.1039/D1CC03477D⟩. ⟨hal-03322399⟩

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