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Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives

Abstract : An unprecedented enantioselective conjugate addition reaction of sodium bisulfite to various nitrostyrenes occurred upon the influence of a bifunctional amino-thiourea organocatalyst; a strategy that opens a straightforward route to unprotected chiral taurine derivatives thanks to the reduction of the obtained β-nitroethanesulfonic acids into the corresponding amino derivatives.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-03322399
Contributor : Jean-François Brière <>
Submitted on : Thursday, August 19, 2021 - 9:53:48 AM
Last modification on : Friday, August 20, 2021 - 3:25:53 AM

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Emmanuel Deau, Alexandra Le Foll, Clémence Fouache, Emilie Corrot, Laetitia Bailly, et al.. Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives. Chemical Communications, Royal Society of Chemistry, In press, ⟨10.1039/D1CC03477D⟩. ⟨hal-03322399⟩

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