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Novel bis-(3-cyano-2-pyridones) derivatives: synthesis and fluorescent properties

Abstract : Novel substituted bis-(3-cyano-2-pyridone) derivatives were prepared via a powerful method using enaminonitriles push-pull dienes as key building blocks. The synthesis was performed in three-steps from easily accessible starting materials in good yields. All target products were structurally elucidated by spectroscopic data. The reaction mechanism for formation of bis (3cyano-2-pyridone) derivatives was proposed. The structures of enaminonitriles 3a and bispyridones 4c were confirmed by single-crystal X-ray diffraction. The florescent study of some bis (3-cyano-2-pyridones) derivatives was reported.
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Submitted on : Tuesday, January 19, 2021 - 8:39:27 AM
Last modification on : Sunday, June 26, 2022 - 3:03:39 AM
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Nawel Mehiaoui, Zahira Kibou, Thibault Gallavardin, Stéphane Leleu, Xavier Franck, et al.. Novel bis-(3-cyano-2-pyridones) derivatives: synthesis and fluorescent properties. Research on Chemical Intermediates, Springer Verlag, 2021, ⟨10.1007/s11164-020-04373-8⟩. ⟨hal-03114546⟩



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