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Stereoselective Synthesis of Pyrrolidines from N -Allyl Oxazolidines via Hydrozirconation−Cyclization

Abstract : A new diastereoselective synthesis of pyrrolidines from readily available chiral N-allyl oxazolidines is presented. The construction of the pyrrolidine ring is achieved via a tandem hydrozirconation−stereoselective Lewis acid mediated cyclization sequence.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02548612
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Submitted on : Monday, April 20, 2020 - 5:53:28 PM
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Jean-Luc Vasse, Antoine Joosten, Clément Denhez, Jan Szymoniak. Stereoselective Synthesis of Pyrrolidines from N -Allyl Oxazolidines via Hydrozirconation−Cyclization. Organic Letters, American Chemical Society, 2005, 7 (22), pp.4887-4889. ⟨10.1021/ol0517776⟩. ⟨hal-02548612⟩

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