Use of Cleavable Coordinating Rings as Protective Groups in the Synthesis of a Rotaxane with an Axis that Incorporates More Chelating Groups Than Threaded Macrocycles - Normandie Université Accéder directement au contenu
Article Dans Une Revue Chemistry - A European Journal Année : 2013

Use of Cleavable Coordinating Rings as Protective Groups in the Synthesis of a Rotaxane with an Axis that Incorporates More Chelating Groups Than Threaded Macrocycles

Antoine Joosten
Yann Trolez
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  • PersonId : 957915
Valérie Heitz
Jean-Pierre Sauvage
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  • PersonId : 922318

Résumé

A new methodology allowing preparation of a linear “unsaturated” [3]rotaxane consisting of an axis incorporating more coordination sites than threaded rings was developed. It was based on the preliminary synthesis of a “saturated” [5]rotaxane consisting of a four‐chelating site axis threaded through four macrocyclic components, two of them being cleavable rings incorporating a lactone function and the two others being “secure” non‐cleavable rings. The stoppering reaction was based on click chemistry. Subsequently, cleavage and removal of the two lactone‐containing macrocycles from the [5]rotaxane in basic medium afforded the desired “unsaturated” [3]rotaxane in quantitative yield.

Domaines

Chimie

Dates et versions

hal-02548575 , version 1 (20-04-2020)

Identifiants

Citer

Antoine Joosten, Yann Trolez, Valérie Heitz, Jean-Pierre Sauvage. Use of Cleavable Coordinating Rings as Protective Groups in the Synthesis of a Rotaxane with an Axis that Incorporates More Chelating Groups Than Threaded Macrocycles. Chemistry - A European Journal, 2013, 19 (38), pp.12815-12823. ⟨10.1002/chem.201301717⟩. ⟨hal-02548575⟩
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