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Journal articles
Functionalization of GlucoPyranosides at position 5 by 1,5 C–H insertion of Rh(II)-Carbenes: Dramatic influence of the anomeric configuration
Abstract : Herein, a C–H bond functionalization approach is reported as a new route towards non-natural glycosides having a quaternary position 5. The development of this transformation furthermore reveals that insertion of Rh(II)-carbenes into the C5–H bond is controlled by remote stereoelectronic effects induced by the axial or equatorial orientation of the aglycone.
https://hal-normandie-univ.archives-ouvertes.fr/hal-02548495
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Submitted on : Tuesday, December 21, 2021 - 11:51:46 AM
Last modification on : Sunday, June 26, 2022 - 3:28:36 AM
Long-term archiving on: : Wednesday, March 23, 2022 - 10:20:16 AM
Contributor : Accord Elsevier CCSD Connect in order to contact the contributor
Submitted on : Tuesday, December 21, 2021 - 11:51:46 AM
Last modification on : Sunday, June 26, 2022 - 3:28:36 AM
Long-term archiving on: : Wednesday, March 23, 2022 - 10:20:16 AM
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