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Synthesis of Various Terphenyl Derivatives; Study of a New Amine Receptor with a Terphenyl Structure

Patricia Le Nahenec-Martel 1 Stéphane Leleu 1 Francis Marsais 1 Cyril Papamicaël 1 Vincent Levacher 1 Georges Dupas 1
1 COBRA - Chimie Organique et Bioorganique : Réactivité et Analyse
Abstract : The synthesis of functionalized terphenyl derivatives was achieved starting from readily available 1,3-dichloro-2-iodobenzene. Among the prepared compounds, a molecule able to bind with benzylamine is described. This new host consist in a terphenyl structure possessing two side arms with aminomethylpyridines moieties. An interesting association constant with benzylamine and an unexpected 2/1 (host/guest) complex have been determined by using 1H NMR dilution experiments.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02547629
Contributor : Madeleine Roux-Merlin <>
Submitted on : Monday, April 20, 2020 - 10:38:41 AM
Last modification on : Thursday, July 2, 2020 - 3:29:26 AM

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COMUE-NORMANDIE | INC-CNRS | INSA-ROUEN | UNIROUEN | COBRA | INSA-GROUPE | CNRS | ENSICAEN | UNILEHAVRE | UNICAEN

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Patricia Le Nahenec-Martel, Stéphane Leleu, Francis Marsais, Cyril Papamicaël, Vincent Levacher, et al.. Synthesis of Various Terphenyl Derivatives; Study of a New Amine Receptor with a Terphenyl Structure. Letters in Organic Chemistry, Bentham Science Publishers, 2005, 2 (2), pp.172-175. ⟨10.2174/1570178053202955⟩. ⟨hal-02547629⟩

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