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Journal articles
Base-Assisted Intramolecular C–N Coupling Reaction from NH 2 -Bound Cyclopalladated L -Phenylalanine to Indoline-2-carboxylic Acid
Abstract : The deprotonative intramolecular-amination reaction of phenylalanine-derived palladacycles has been investigated to highlight a facile carbonate-assisted N–H activation before the C–N bond formation. A major counterion effect led to divergent pathways whereby the SPhos-Pd complexes with iodine, triflate, or trifluoroacetate anions were key intermediates to afford access to (S)-2-indolinecarboxylic acid derivatives.
Cited literature [11 references]
https://hal-normandie-univ.archives-ouvertes.fr/hal-02493098
Contributor : Jean-François Brière <>
Submitted on : Friday, August 21, 2020 - 10:56:04 AM
Last modification on : Saturday, May 1, 2021 - 3:51:07 AM
Long-term archiving on: : Tuesday, December 1, 2020 - 4:16:30 AM
Contributor : Jean-François Brière <>
Submitted on : Friday, August 21, 2020 - 10:56:04 AM
Last modification on : Saturday, May 1, 2021 - 3:51:07 AM
Long-term archiving on: : Tuesday, December 1, 2020 - 4:16:30 AM
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Organometallics2020(a).pdf
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