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Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

Daouda Ndiaye 1 Sébastien Coufourier 1 Mbaye Diagne Mbaye 2 Sylvain Gaillard 1 Jean-Luc Renaud 1 
1 LCMT - Laboratoire de chimie moléculaire et thioorganique
2 UASZ - Université Assane SECK de Ziguinchor
Abstract : The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.
Keywords : Iron complexes Hydrogen transfer Reductive amination Alcohols Amines
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02490284
Contributor : Jean-Luc RENAUD Connect in order to contact the contributor
Submitted on : Tuesday, February 25, 2020 - 9:56:55 AM
Last modification on : Sunday, June 26, 2022 - 2:47:27 AM

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Daouda Ndiaye, Sébastien Coufourier, Mbaye Diagne Mbaye, Sylvain Gaillard, Jean-Luc Renaud. Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water. Molecules, MDPI, 2020, 25 (2), pp.421. ⟨10.3390/molecules25020421⟩. ⟨hal-02490284⟩

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