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Sequential friedel-crafts-type α-amidoalkylation/intramolecular hydroarylation Distinct advantage of combined Tf2NH/cationic LAu(I) as a consecutive or binary bicatalytic system

Abstract : The combined use of Tf2NH and L(Au)+X- as a dual or binary catalytic system clearly improves the efficiency and enlarges the scope of the tandem intermolecular Friedel-Crafts α-amidoalkylation/intramolecular hydroarylation sequence, compared to an "all gold" multicatalysis approach. © 2015 American Chemical Society.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02413298
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Submitted on : Monday, December 16, 2019 - 10:44:27 AM
Last modification on : Tuesday, June 16, 2020 - 11:28:03 AM

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Liliana Boiaryna, Mohamed Salah Azizi, Abderrahman El Bouakher, Baptiste Picard, Catherine Taillier, et al.. Sequential friedel-crafts-type α-amidoalkylation/intramolecular hydroarylation Distinct advantage of combined Tf2NH/cationic LAu(I) as a consecutive or binary bicatalytic system. Organic Letters, American Chemical Society, 2015, 17 (9), pp.2130-2133. ⟨10.1021/acs.orglett.5b00718⟩. ⟨hal-02413298⟩

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