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Rhodium-Catalyzed Hydroamination of Ethylene. Highly Promoting Effect of Iodide Ions

Abstract : Association of the usual “RhCl3−3H2O−2PPh3” catalytic precursor (0.3%) with n-Bu4PI (65 equiv/Rh) and iodine (2 equiv/Rh) generates the most active catalytic system reported so far for the hydroamination of ethylene with aniline to give mixtures of N-ethyl- and N,N-diethylanilines. This system proved particularly efficient for the hydroamination of ethylene with N-ethylaniline (TON > 260 after 24 h).
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02385356
Contributor : Christine Baudequin <>
Submitted on : Thursday, November 28, 2019 - 5:26:57 PM
Last modification on : Wednesday, July 15, 2020 - 4:51:51 PM

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Christine Baudequin, Jean-Jacques Brunet, Mireia Rodriguez-Zubiri. Rhodium-Catalyzed Hydroamination of Ethylene. Highly Promoting Effect of Iodide Ions. Organometallics, American Chemical Society, 2007, 26 (22), pp.5264-5266. ⟨10.1021/om7009073⟩. ⟨hal-02385356⟩

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