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Journal Articles Organometallics Year : 2007

Rhodium-Catalyzed Hydroamination of Ethylene. Highly Promoting Effect of Iodide Ions

Abstract

Association of the usual “RhCl3−3H2O−2PPh3” catalytic precursor (0.3%) with n-Bu4PI (65 equiv/Rh) and iodine (2 equiv/Rh) generates the most active catalytic system reported so far for the hydroamination of ethylene with aniline to give mixtures of N-ethyl- and N,N-diethylanilines. This system proved particularly efficient for the hydroamination of ethylene with N-ethylaniline (TON > 260 after 24 h).

Dates and versions

hal-02385356 , version 1 (28-11-2019)

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Christine Baudequin, Jean-Jacques Brunet, Mireia Rodriguez-Zubiri. Rhodium-Catalyzed Hydroamination of Ethylene. Highly Promoting Effect of Iodide Ions. Organometallics, 2007, 26 (22), pp.5264-5266. ⟨10.1021/om7009073⟩. ⟨hal-02385356⟩
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