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Synthesis and stereochemistry of some new 1,3,5-tris(1,3-dioxan-2-yl)-benzene derivatives

Abstract : The synthesis and the stereochemistry of new 1,3,5-tris(1,3-dioxan-2-yl)-benzene derivatives are reported. The anancomeric structure and the axial orientation of the aryl group with respect to all 1,3-dioxane rings, and the cis-trans isomerism of some of the compounds are revealed. The data are supported by NMR investigations and by the molecular structure of one compound determined by single crystal X-ray diffractometry.
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Submitted on : Wednesday, June 9, 2021 - 3:40:33 PM
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Maria Florian, Monica Cîrcu, Loic Toupet, Anamaria Terec, Ion Grosu, et al.. Synthesis and stereochemistry of some new 1,3,5-tris(1,3-dioxan-2-yl)-benzene derivatives. Central European Journal of Chemistry, Springer Verlag, 2006, 4 (4), pp.808-821. ⟨10.2478/s11532-006-0040-2⟩. ⟨hal-02385181⟩



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