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Regioselective opening of N-Cbz glutamic and aspartic anhydrides with carbon nucleophiles

Abstract : Depending on the experimental conditions, aspartic and glutamic anhydrides can be opened regioselectively with Grignard reagents, thus giving access to different isomers of chiral amino-ketoesters.
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Submitted on : Thursday, November 28, 2019 - 4:08:49 PM
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Geoffrey Deguest, Laurent Bischoff, Corinne Fruit, Francis Marsais. Regioselective opening of N-Cbz glutamic and aspartic anhydrides with carbon nucleophiles. Tetrahedron: Asymmetry, Elsevier, 2006, 17 (14), pp.2120-2125. ⟨10.1016/j.tetasy.2006.07.039⟩. ⟨hal-02385048⟩

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