Regioselective opening of N-Cbz glutamic and aspartic anhydrides with carbon nucleophiles - Archive ouverte HAL Access content directly
Journal Articles Tetrahedron: Asymmetry Year : 2006

Regioselective opening of N-Cbz glutamic and aspartic anhydrides with carbon nucleophiles

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Abstract

Depending on the experimental conditions, aspartic and glutamic anhydrides can be opened regioselectively with Grignard reagents, thus giving access to different isomers of chiral amino-ketoesters.

Dates and versions

hal-02385048 , version 1 (28-11-2019)

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Geoffrey Deguest, Laurent Bischoff, Corinne Fruit, Francis Marsais. Regioselective opening of N-Cbz glutamic and aspartic anhydrides with carbon nucleophiles. Tetrahedron: Asymmetry, 2006, 17 (14), pp.2120-2125. ⟨10.1016/j.tetasy.2006.07.039⟩. ⟨hal-02385048⟩
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