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Stereocontrolled Solid-Phase Synthesis of a 90-Membered Library of Indoline-Alkaloid-like Polycycles from an Enantioenriched Aminoindoline Scaffold

Abstract : A library of tricyclic derivatives, similar to indoline alkaloids, has been generated by using a stereocontrolled, conjugate hetero‐Michael approach in both the solution and the solid phase (see scheme; P=protecting group, R=functional group). The mild reaction conditions that lead to the tricyclic derivatives, which contain β‐amino acid functionalities, are highly attractive.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02384481
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Submitted on : Thursday, November 28, 2019 - 1:49:06 PM
Last modification on : Tuesday, November 3, 2020 - 9:50:05 AM

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Zhonghong Gan, P. Thirupathi Reddy, Sophie Quévillon, Samuel Couve-Bonnaire, Prabhat Arya. Stereocontrolled Solid-Phase Synthesis of a 90-Membered Library of Indoline-Alkaloid-like Polycycles from an Enantioenriched Aminoindoline Scaffold. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2005, 44 (9), pp.1366-1368. ⟨10.1002/anie.200462298⟩. ⟨hal-02384481⟩

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