Insight in chitosan aerogels derivatives -Application in catalysis

Abstract : Thanks to an aerogel formulation, an efficient heterogeneous modification of chitosan is described and offers the convenient covalent-functionalisation of primary amine of insoluble microspheres into secondary benzylic-amines with various functionalities. The SEC, XRD and textural analyses provided a better insight into the chitosan aerogels and showed that this synthetic process allows high substitution ratio (> 80%) without depressing the desirable properties of the well-defined chitosan macromolecular structure. As a proof of principle, original catalytic chitosan aerogels flanked by a phosphine-pendant were prepared and applied successfully in the heterogenous pallado-catalyzed allylic substitution reaction.
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Contributeur : Jean-François Brière <>
Soumis le : vendredi 22 novembre 2019 - 17:03:54
Dernière modification le : jeudi 13 février 2020 - 09:16:30

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Ronan Le Goff, Olivier Mahé, Ronan Le Coz-Botrel, Sylvie Malo, Jean-Michel Goupil, et al.. Insight in chitosan aerogels derivatives -Application in catalysis. Reactive and Functional Polymers, Elsevier, 2020, 146, pp.104393. ⟨10.1016/j.reactfunctpolym.2019.104393⟩. ⟨hal-02376706⟩



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