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Journal articles
Abnormal Grain Growth as a Method To Enhance the Thermoelectric Performance of Nb-Doped Strontium Titanate Ceramics
Abstract : Driven by the need for high-temperature n-type thermoelectrics for energy-harvesting sectors, SrTi0.8Nb0.2O3±δ ceramics are prepared here from powders with average particle sizes of 270 and 800 nm by the conventional sintering in air at 1450 °C and further in H2/N2 at 1400 °C. In contrast to coarse particle powders, the use of fine particle powders under these conditions leads to abnormal grain growth and thereby bimodal grain size distribution in SrTi0.8Nb0.2O3±δ ceramics. As a result, a 3-fold increase in the thermoelectric figure of merit to 0.36 at 970 K is achieved, thus establishing the record value for bulk Nb-doped strontium titanate up to this temperature.
Cited literature [30 references]
https://hal-normandie-univ.archives-ouvertes.fr/hal-02327407
Contributor : Emmanuel Guilmeau <>
Submitted on : Friday, November 8, 2019 - 3:21:56 PM
Last modification on : Monday, July 20, 2020 - 10:06:05 AM
Contributor : Emmanuel Guilmeau <>
Submitted on : Friday, November 8, 2019 - 3:21:56 PM
Last modification on : Monday, July 20, 2020 - 10:06:05 AM
