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Journal articles
Iron-Catalyzed β-Alkylation of Alcohols
Abstract : β-Branched alkylated alcohols have been prepared in good yields using a double-hydrogen autotransfer strategy in the presence of our diaminocyclopentadienone iron tricarbonyl complex Fe1. The alkylation of some 2-arylethanol derivatives was successfully addressed with benzylic alcohols and methanol as alkylating reagents under mild conditions. Deuterium labeling experiments suggested that both alcohols (2-arylethanol and either methanol or benzyl alcohol) served as hydrogen donors in this cascade process.
https://hal-normandie-univ.archives-ouvertes.fr/hal-02308190
Contributor : Jean-Luc Renaud Connect in order to contact the contributor
Submitted on : Tuesday, October 8, 2019 - 1:12:29 PM
Last modification on : Tuesday, January 4, 2022 - 5:56:17 AM
Contributor : Jean-Luc Renaud Connect in order to contact the contributor
Submitted on : Tuesday, October 8, 2019 - 1:12:29 PM
Last modification on : Tuesday, January 4, 2022 - 5:56:17 AM
