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Article dans une revue
Iron-Catalyzed β-Alkylation of Alcohols
Abstract : β-Branched alkylated alcohols have been prepared in good yields using a double-hydrogen autotransfer strategy in the presence of our diaminocyclopentadienone iron tricarbonyl complex Fe1. The alkylation of some 2-arylethanol derivatives was successfully addressed with benzylic alcohols and methanol as alkylating reagents under mild conditions. Deuterium labeling experiments suggested that both alcohols (2-arylethanol and either methanol or benzyl alcohol) served as hydrogen donors in this cascade process.
https://hal-normandie-univ.archives-ouvertes.fr/hal-02308190
Contributeur : Jean-Luc Renaud <>
Soumis le : mardi 8 octobre 2019 - 13:12:29
Dernière modification le : jeudi 2 juillet 2020 - 03:21:25
Contributeur : Jean-Luc Renaud <>
Soumis le : mardi 8 octobre 2019 - 13:12:29
Dernière modification le : jeudi 2 juillet 2020 - 03:21:25
