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Double Cationic-Anionic Ordering in Ba-Based Oxygen-Deficient Perovskites

Abstract : Complex cationic-anionic ordering in barium-based oxygen deficient perovskites is reviewed. Considering the parent ABO3 structure, the ordering between barium and a rare earth cation in the A site generates three classes of oxides, called double, triple and nanoscale ordered quintuple perovskites. From the ordering between a transition element (Fe, Co) and a larger cation on the B site two structural families are obtained, containing calcium and yttrium respectively. These oxides offer a vast playground for the investigation of magnetic and transport properties. Copyright © 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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Submitted on : Monday, July 15, 2019 - 6:06:59 PM
Last modification on : Thursday, November 24, 2022 - 4:05:35 AM

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B. Raveau, V. Caignaert, A.K. Kundu. Double Cationic-Anionic Ordering in Ba-Based Oxygen-Deficient Perovskites. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2015, Special Issue: Dedicated to Professor Rüdiger Kniep on the Occasion of His 70th Birthday, 641 (6), pp.990-997. ⟨10.1002/zaac.201500088⟩. ⟨hal-02184182⟩



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