Charge ordering in cobalt oxides Impact on structure, magnetic and transport properties

B. Raveau (1) , M.M. Seikh (2)

1 CRISMAT - Laboratoire de cristallographie et sciences des matériaux
2 Department of Chemistry, Visva Bharati University

This review shows the great impact of charge ordering upon the magnetic and transport properties of mixed valent Co4+/Co3+ and Co3+/Co2+ cobalt oxides. The relationships between charge ordering and physical properties are described for three structural families the ordered oxygen deficient perovskites and the Ruddlesden and Popper (RP) derivative La1.5Sr0.5CoO4, the layered NaxCoO2 series and the "114" CaBaCo4O7 oxide. Copyright © 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Keywords: Charge ordering; Cobalt oxide; Cobaltate; Perovskite; Spin ordering

Domains: Chemical Sciences; Chemical Sciences; Cristallography; Chemical Sciences; Material chemistry; Chemical Sciences; Theoretical and/or physical chemistry

B. Raveau, M.M. Seikh. Charge ordering in cobalt oxides Impact on structure, magnetic and transport properties. Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2015, Special Issue: Dedicated to Professor Juri Grin on the Occasion of His 60th Birthday, 641 (8-9), pp.1385-1394. ⟨10.1002/zaac.201500085⟩. ⟨hal-02184158⟩