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Phase equilibria in the Zn-Mn-O system

Abstract : Different ratios of ZnO and MnCO3 were mixed and processed by ceramic route to investigate phase relations in the Zn-Mn-O system using differential thermal analysis and X-ray powder diffraction techniques. Except for Zn1-xMnxO we detected two different spinel phases in this system. FactSage program was used for the construction of the Zn-Mn-O phase diagram in air and oxygen atmosphere. To verify the composition in several parts of the diagram at the temperature of interest, a number of high-temperature annealings followed by quenching was performed. © 2014 Elsevier Ltd.
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L. Nádherný, O. Jankovský, Z. Sofer, J. Leitner, Christine Martin, et al.. Phase equilibria in the Zn-Mn-O system. Journal of the European Ceramic Society, Elsevier, 2015, 35 (2), pp.555-560. ⟨10.1016/j.jeurceramsoc.2014.09.008⟩. ⟨hal-02184136⟩



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