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Bifunctional Iron Complexes Catalyzed Alkylation of Indoles

Abstract : Cyclopentadienone iron carbonyl complexes have been applied in alkylation of indoles with various benzylic alcohols, aliphatic alcohols (butanol, ethanol, methanol and 2‐methylpentanol) via the hydrogen autotransfer strategy in mild reaction conditions. Experimental works highlight the role of the bifunctional iron complexes and the base. These iron complexes demonstrated a broad applicability in mild conditions and extended the scope of substrates in iron catalyzed C−C bond formation.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02159937
Contributor : Jean-Luc Renaud <>
Submitted on : Wednesday, June 19, 2019 - 10:45:34 AM
Last modification on : Thursday, July 2, 2020 - 3:21:26 AM

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Charlotte Seck, Mbaye Diagne Seck, Sylvain Gaillard, Jean-Luc Renaud. Bifunctional Iron Complexes Catalyzed Alkylation of Indoles. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (23), pp.4640-4645. ⟨10.1002/adsc.201800924⟩. ⟨hal-02159937⟩

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