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BiCl 3 -Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF 2 PO(OEt) 2 reagent

Abstract : A transition metal-free approach was developed for the direct difunctionalization of disubstituted alkynes and terminal alkenes with concomitant formation of C–SCF2PO(OEt)2 and C–Cl bonds. The BiCl3-mediated reaction offered access to high value-added functionalized scaffolds in a single operation under mild conditions. Extension to SCF2PO(OEt)2-containing alkynes was also studied.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02121245
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Submitted on : Thursday, May 16, 2019 - 6:14:51 PM
Last modification on : Wednesday, July 8, 2020 - 2:08:03 PM

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Jianjun Wang, Heng-Ying Xiong, Emilie Petit, Laëtitia Bailly, Xavier Pannecoucke, et al.. BiCl 3 -Mediated direct functionalization of unsaturated C–C bonds with an electrophilic SCF 2 PO(OEt) 2 reagent. Chemical Communications, Royal Society of Chemistry, 2019, 55 (60), pp.8784-8787. ⟨10.1039/c9cc01851d⟩. ⟨hal-02121245⟩

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