 |
Journal articles
Palladium-Catalyzed Carbonylation of (Hetero)Aryl, Alkenyl and Allyl Halides by Means of N-Hydroxysuccinimidyl Formate as CO Surrogate
Abstract : An efficient Pd-catalyzed carbonylation protocol is described for the coupling of a large panel of aryl, heteroaryl, benzyl, vinyl and allyl halides 2 with the unusual N-hydroxysuccinimidyl (NHS) formate 1 as a CO surrogate to afford the corresponding valuable NHS esters 3. High conversion to the coupling products was achieved with up to 98% yield by means of Pd(OAc)2/Xantphos catalyst system.
https://hal-normandie-univ.archives-ouvertes.fr/hal-02046139
Contributor : Madeleine Roux-Merlin <>
Submitted on : Friday, February 22, 2019 - 3:31:52 PM
Last modification on : Wednesday, January 6, 2021 - 11:44:04 AM
Contributor : Madeleine Roux-Merlin <>
Submitted on : Friday, February 22, 2019 - 3:31:52 PM
Last modification on : Wednesday, January 6, 2021 - 11:44:04 AM
