Recent Advances in NMR: Aggregation, Solvation, and Dynamics of Selected Organolithium Compounds - Archive ouverte HAL Access content directly
Journal Articles Synthesis: Journal of Synthetic Organic Chemistry Year : 2018

Recent Advances in NMR: Aggregation, Solvation, and Dynamics of Selected Organolithium Compounds

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Abstract

Nuclear magnetic resonance (NMR) spectroscopy is the most widely used analytical technique to study the structure and dynamics of organolithium compounds, which are the most popular reagents in organic synthesis due to their great diversity and high reactivity. The main strength of this method is that it allows direct analysis in solution of the aggregation, dynamic, and solvation state of reactive intermediates. In this review, we present the NMR tools (nD) involving the 6Li isotope and DOSY experiments with internal references and illustrate their contribution in the structural and dynamic characterization of organolithium compounds in solution through some selected example.
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hal-02024522 , version 1 (19-02-2019)

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Hassan Oulyadi. Recent Advances in NMR: Aggregation, Solvation, and Dynamics of Selected Organolithium Compounds. Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (18), pp.3603-3614. ⟨10.1055/s-0037-1610162⟩. ⟨hal-02024522⟩
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