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Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols

Abstract : Lithium imide enolates featuring Evans’ chiral oxazolidinone auxiliary were involved in diastereoselective α‐trifluoromethylthiolation with electrophilic SCF3 donors. Diastereopure products were isolated and converted to enantiopure α‐SCF3 alcohols without racemisation.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02024484
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Submitted on : Tuesday, February 19, 2019 - 11:09:08 AM
Last modification on : Saturday, June 25, 2022 - 9:52:54 AM

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Hélène Chachignon, Evgeniy V. Kondrashov, Dominique Cahard. Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (5), pp.965-971. ⟨10.1002/adsc.201701474⟩. ⟨hal-02024484⟩

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