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Article Dans Une Revue Chemical Communications Année : 2018

An electrophilic reagent for the synthesis of OCHFMe-containing molecules

Résumé

Herein the synthesis of a novel and bench stable electrophilic reagent to construct the OCFHMe motif from O-nucleophiles has been described. This sulfonium salt, readily obtained in 5 steps, reacted with various phenols and alcohols. The resulting products, including complex molecules, were obtained in good yields. This reagent was also used for the functionalization of thiol derivatives.

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Chimie
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Dates et versions

hal-02024482 , version 1 (19-02-2019)

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Elodie Carbonnel, Xavier Pannecoucke, Tatiana Besset, Philippe Jubault, Thomas Poisson. An electrophilic reagent for the synthesis of OCHFMe-containing molecules. Chemical Communications, 2018, 54 (20), pp.2491-2493. ⟨10.1039/c8cc00921j⟩. ⟨hal-02024482⟩
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