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Article Dans Une Revue European Journal of Organic Chemistry Année : 2018

Synthesis of α-Fluorinated Acrylates by a Palladium-Catalyzed Decarboxylative Olefination Reaction

Résumé

Ligand‐free palladium‐catalyzed subsequent decarboxylation/olefination reaction between 2‐fluorinated acrylates and benzoic acids is reported. Valuable trisubstituted 2‐fluoroacrylates and 2‐trifluoromethylacrylates were produced in low to excellent yields, which constitutes a new interesting greener synthetic alternative to these fluorinated molecules.

Domaines

Chimie
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Dates et versions

hal-02024480 , version 1 (19-02-2019)

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Citer

Ouafa Bouazzaoui, Kevin Rousée, Joseph Kajima Mulengi, Xavier Pannecoucke, J.-P. Bouillon, et al.. Synthesis of α-Fluorinated Acrylates by a Palladium-Catalyzed Decarboxylative Olefination Reaction. European Journal of Organic Chemistry, 2018, Special Issue: Organofluorine Chemistry in Europe, 2018 (27-28), pp.3705-3715. ⟨10.1002/ejoc.201701709⟩. ⟨hal-02024480⟩
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