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Synthesis of α-Fluorinated Acrylates by a Palladium-Catalyzed Decarboxylative Olefination Reaction

Abstract : Ligand‐free palladium‐catalyzed subsequent decarboxylation/olefination reaction between 2‐fluorinated acrylates and benzoic acids is reported. Valuable trisubstituted 2‐fluoroacrylates and 2‐trifluoromethylacrylates were produced in low to excellent yields, which constitutes a new interesting greener synthetic alternative to these fluorinated molecules.
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https://hal-normandie-univ.archives-ouvertes.fr/hal-02024480
Contributor : Madeleine Roux-Merlin <>
Submitted on : Tuesday, February 19, 2019 - 11:09:02 AM
Last modification on : Thursday, July 2, 2020 - 3:29:19 AM

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Ouafa Bouazzaoui, Kevin Rousée, Joseph Kajima Mulengi, Xavier Pannecoucke, J.-P. Bouillon, et al.. Synthesis of α-Fluorinated Acrylates by a Palladium-Catalyzed Decarboxylative Olefination Reaction. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2018, Special Issue: Organofluorine Chemistry in Europe, 2018 (27-28), pp.3705-3715. ⟨10.1002/ejoc.201701709⟩. ⟨hal-02024480⟩

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