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Article Dans Une Revue Chemical Engineering Science Année : 2007

Kinetic study of decomposition of peroxypropionic acid in liquid phase through direct analysis of decomposition products in gas phase

Tapio Salmi
  • Fonction : Auteur
Niko Musakka
  • Fonction : Auteur
Johan Wärnå
  • Fonction : Auteur

Résumé

Decomposition of peroxypropionic acid (PPA) takes place in the liquid phase, but the main products of decomposition, carbon dioxide and oxygen are transferred to gas phase. An analytical method was developed to determine the decomposition of PPA in liquid phase by means of chemical analysis of gas phase. The method is based on on-line mass spectroscopy (MS). A mathematical model for the semi-batch gas–liquid system was developed. The model comprised both kinetic and mass transfer effects. A comparison between experimental results and results predicted from the mathematical model revealed that the model can describe the essential effects of decomposition kinetics.

Dates et versions

hal-02017689 , version 1 (13-02-2019)

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Citer

Sébastien Leveneur, Tapio Salmi, Niko Musakka, Johan Wärnå. Kinetic study of decomposition of peroxypropionic acid in liquid phase through direct analysis of decomposition products in gas phase. Chemical Engineering Science, 2007, 62 (18-20), pp.5007-5012. ⟨10.1016/j.ces.2006.12.040⟩. ⟨hal-02017689⟩
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