Microwave-irridation and flow chemistry for a straightforward synthesis of piano-stool iron complexes

A. Pagnoux-Ozherelyeva (1) , Sd. Bolien (2) , F. Peudru (1) , J.-F Lohier (1) , Sylvain Gaillard (1) , Richard J. Whitby (2) , J. L. Renaud (1)

1 LCMT - Laboratoire de chimie moléculaire et thioorganique
2 University of Southampton

Two series of piano-stool iron(II) complexes bearing bidentate phosphine or mixed phosphorus–nitrogen ligands have been prepared upon reaction with CpFe(CO)2I or [CpFe(naphthalene)][PF6] under microwave irradiation or using flow chemistry.

Mots clés: Iron; Microwave; Flow chemistry; Organometallic synthesis

Domaines: Chimie

A. Pagnoux-Ozherelyeva, Sd. Bolien, F. Peudru, J.-F Lohier, Sylvain Gaillard, et al.. Microwave-irridation and flow chemistry for a straightforward synthesis of piano-stool iron complexes. Journal of Organometallic Chemistry, 2014, 774, pp.35-42. ⟨10.1016/j.jorganchem.2014.09.031⟩. ⟨hal-01848077⟩