Abstract : An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero)arylamines. This fast reaction (35 min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.
https://hal-normandie-univ.archives-ouvertes.fr/hal-01793145 Contributor : Jérôme BlanchetConnect in order to contact the contributor Submitted on : Wednesday, May 16, 2018 - 11:26:15 AM Last modification on : Thursday, December 9, 2021 - 3:54:03 PM