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An Easy Route to (Hetero)arylboronic Acids

William Erb 1 Akila Hellal 1 Mathieu Albini 1 Jacques Rouden 1 Jerome Blanchet 1
1 LCMT - Laboratoire de chimie moléculaire et thioorganique
Abstract : An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero)arylamines. This fast reaction (35 min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.
Keywords : aromatics diazo compounds heterocyclic compounds pseudohalogens radicals
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Journal articles
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https://hal-normandie-univ.archives-ouvertes.fr/hal-01793145
Contributor : Jérôme Blanchet <>
Submitted on : Wednesday, May 16, 2018 - 11:26:15 AM
Last modification on : Friday, November 13, 2020 - 10:46:02 AM

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COMUE-NORMANDIE | CNRS | ENSICAEN | UNICAEN | LCMT | INSA-ROUEN | UNIROUEN | UNILEHAVRE | INSA-GROUPE

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William Erb, Akila Hellal, Mathieu Albini, Jacques Rouden, Jerome Blanchet. An Easy Route to (Hetero)arylboronic Acids. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (22), pp.6608 - 6612. ⟨10.1002/chem.201402487⟩. ⟨hal-01793145⟩

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