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Journal articles
Borinic Acid Catalysed Reduction of Tertiary Amides with Hydrosilanes: A Mild and Chemoselective Synthesis of Amines
Abstract : A reduction of various aryl, alkyl, and α,β‐unsaturated amides with phenylsilane, catalysed by a borinic acid, is reported. The unprecedented reaction was carried out under very mild conditions and led to useful amines. Furthermore, the reaction tolerates a variety of functional groups. Initial investigations implicated that an intermediate diarylhydroborane is involved in the reaction mechanism.
https://hal-normandie-univ.archives-ouvertes.fr/hal-01793130
Contributor : Jérôme Blanchet <>
Submitted on : Wednesday, May 16, 2018 - 11:22:02 AM
Last modification on : Friday, November 13, 2020 - 10:46:02 AM
Contributor : Jérôme Blanchet <>
Submitted on : Wednesday, May 16, 2018 - 11:22:02 AM
Last modification on : Friday, November 13, 2020 - 10:46:02 AM
