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Journal Articles Organic Letters Year : 2022

Organophotocatalysis Enables the Synthesis of gem-FluoroPhosphonate Alkenes

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Abstract

gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10methylacridinium perchlorate) as organic photocatalyst, to provide valuables gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields and the reaction showed very good chemical tolerance. .
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Dates and versions

hal-03863948 , version 1 (21-11-2022)

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Solène Morand, William Lecroq, Philippe Jubault, Sami Lakhdar, Jean-Philippe Bouillon, et al.. Organophotocatalysis Enables the Synthesis of gem-FluoroPhosphonate Alkenes. Organic Letters, 2022, 24 (45), pp.8343-8347. ⟨10.1021/acs.orglett.2c03366⟩. ⟨hal-03863948⟩
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